The 35-year-old donned an elegant floor length gown with a gold chain, enhancing the ensemble’s asymmetric one shoulder look.
The natural beauty had subtle glam featuring a delicate smokey eye and winged liner, while she wore her brunette locks were kept back in a chic updo.
Antonela kept her jewellery simple and accessorised with simple gold hoop earrings and rings.
Meanwhile, her husband Messi, 36, looked very dapper with a sharp black suit with a white shirt and a black bow tie.
The couple’s three sons, Thiago, 10, Mateo, seven, and Ciro, five, stood proudly together for the red carpet paparazzi.
The sons were also dressed to impress with all three wearing black suits and white shirts, however keeping to their adolescent style with pristine white trainers.